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Merck

76023AST

Supelco

Astec® CHIRALDEX B-PM Capillary GC Column

L × I.D. 30 m × 0.25 mm, df 0.12 μm

Synonym(e):

GC column, chiral, beta-dextran

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About This Item

UNSPSC-Code:
41115710
eCl@ss:
32110502
NACRES:
SB.54

Materialien

fused silica

Beschreibung

GC capillary column

Verpackung

pkg of 1 ea

Parameter

-10-200 °C temperature (isothermal)
-10-220 °C temperature (programmed)

Beta-Wert

500

df

0.12 μm

Methode(n)

gas chromatography (GC): suitable

L × ID

30 m × 0.25 mm

Aktive Matrixgruppe

non-bonded; 2,3,6-tri-O-methyl derivative of β-cyclodextrin phase

Anwendung(en)

agriculture
chemicals and industrial polymers
cleaning products
clinical
cosmetics
environmental
flavors and fragrances
food and beverages
forensics and toxicology
life science and biopharma
personal care
pharmaceutical (small molecule)

Säulenart

capillary chiral

Trenntechnik

chiral

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Allgemeine Beschreibung

The main difference between CHIRALDEX B-PM and the Supelco β-DEX 110 and Supelco β-DEX 120 phases is the concentration of the permethyl-derivatized cyclodextrin that is doped into the polysiloxane carrier. CHIRALDEX B-PM is a general-purpose column used for the separation of acids, alcohols, barbitals, diols, epoxides, esters, hydrocarbons, ketones, lactones and terpenes. Also, some underivatized alcohols and diols as well as some analytes with polar groups, i.e. tertiary amines, show excellent separation.

Chemische/physikalische Beständigkeit

Temp. Limits:
  • -10 °C to 200 °C isothermal, 220 °C programmed

Sonstige Hinweise

We offer a variety of chromatography accessories including analytical syringes

Rechtliche Hinweise

Astec is a registered trademark of Merck KGaA, Darmstadt, Germany
CHIRALDEX is a trademark of Sigma-Aldrich Co. LLC

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Recent development of cationic cyclodextrins for chiral separation
Zhou, Jie, et al.
TrAC, Trends in Analytical Chemistry, 65, 22-29 (2015)
C Freissinet et al.
Journal of chromatography. A, 1306, 59-71 (2013-08-08)
The performances of several commercial chiral capillary columns have been evaluated with the aim of determining the one most suitable for enantiomeric separation in a gas chromatograph onboard a space probe. We compared the GC-MS response of three capillary columns
Synthesis of enantiopure ?2-homoalanine derivatives via rhodium catalyzed asymmetric hydrogenation
Luhr, Susan, et al.
Tetrahedron, 24 (7), 395-401 (2013)
Ionic cyclodextrins in ionic liquid matrices as chiral stationary phases for gas chromatography
Huang, Ke, et al.
Tetrahedron Asymmetry, 1217 (32), 5261-5273 (2010)
Izabela Kania-Korwel et al.
Journal of chromatography. A, 1278, 133-144 (2013-01-26)
Changes in the enantiomeric fraction of chiral polychlorinated biphenyls (PCBs) are a powerful tool to investigate the movement of PCBs in the environment, for example as part of source apportionment and ecological studies. Environmental studies typically employ a series of

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