93397

Tris(tetrabutylammonium)-hydrogenpyrophosphat

≥97.0% (calc. on dry substance, T)

• Synonym(e): Pyrophosphorsäure, Tetrabutylammoniumpyrophosphat (3:1)
• Lineare Formel: [(CH₃CH₂CH₂CH₂)₄N⁺]₃[O=P(O^-)₂OP(=O)(O^-)OH]
• CAS-Nummer: 76947-02-9
• Molekulargewicht: 902.34
• Beilstein: 4632762
• MDL-Nummer: MFCD00210109
• UNSPSC-Code: 12352116
• PubChem Substanz-ID: 57653501
• NACRES: NA.22

Eigenschaften

• Assay: ≥97.0% (calc. on dry substance, T)
• Form: crystals
• Verunreinigungen: ≤8% water
• Lagertemp.: 2-8°C
• SMILES String: OP([O-])(=O)OP([O-])([O-])=O.CCCC[N+](CCCC)(CCCC)CCCC.CCCC[N+](CCCC)(CCCC)CCCC.CCCC[N+](CCCC)(CCCC)CCCC
• InChI: 1S/3C16H36N.H4O7P2/c3*1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;1-8(2,3)7-9(4,5)6/h3*5-16H2,1-4H3;(H2,1,2,3)(H2,4,5,6)/q3*+1;/p-3
• InChIKey: BMTUFQKYWWLCLC-UHFFFAOYSA-K

Beschreibung

Anwendung

• The Role of the Maleimide Ring System on the Structure-Activity Relationship of Showdomycin: Discusses unexpected triphosphorylation involving Tris(tetrabutylammonium) hydrogen pyrophosphate (P Rosenqvist et al. - European Journal of Organic Chemistry, 2022).


• Chemical Approaches to Inhibitors of Isoprenoid Biosynthesis: Mentions the reduction of ester group in the context of pyrophosphate chemistry (P Merino et al. - RSC Advances, 2017).


• Emissive Synthetic Cofactors: Involves Tris(tetrabutylammonium) hydrogen pyrophosphate in the synthesis of an ATP analog (J Feldmann, Y Li, Y Tor - Chemistry-A European Journal, 2019).

Sonstige Hinweise

Reagenz für die Pyrophosphorylierung; Reaktion von Isoprenoidderivativen; Pyrophosphorylierung von Nukleosiden; Triphosphorylierung von Nukleosiden

Sicherheitshinweise

• Piktogramme: GHS07
• Signalwort: Warning
• H-Sätze: H315,H319,H335
• P-Sätze: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Gefahreneinstufungen: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• Zielorgane: Respiratory system
• Lagerklassenschlüssel: 11 - Combustible Solids
• WGK: WGK 3
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable
• Persönliche Schutzausrüstung: dust mask type N95 (US), Eyeshields, Gloves