A Pd(II)-catalyzed ring-expansion reaction of cyclic 2-azidoalcohol derivatives: synthesis of azaheterocycles.

A Pd(II)-catalyzed ring-expansion reaction of cyclic 2-azidoalcohol derivatives: synthesis of azaheterocycles.

Journal of the American Chemical Society (2009-08-25)

Shunsuke Chiba, Yan-Jun Xu, Yi-Feng Wang

PMID19697931

RÉSUMÉ

A Pd(II)-catalyzed ring expansion-reaction of cyclic 2-azidoalcohol derivatives was found to proceed via an unprecedented C-C bond cleavage-C-N bond formation sequence, providing substituted azaheterocycles.

MATÉRIAUX

Référence du produit

Marque

Description du produit

697230

Sigma-Aldrich

[1,1′-bis(diphénylphosphino)ferrocène]dichloropalladium(II)