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Silver-mediated fluorination of aryl silanes.

Tetrahedron (2011-06-22)
Pingping Tang, Tobias Ritter
RÉSUMÉ

A regiospecific silver-mediated fluorination of aryl silanes is reported. The reaction is operationally simple, and employs Ag(2)O as readily available, inexpensive silver source, which can be recovered.

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Sigma-Aldrich
1-Fluoro-3-nitrobenzene, 97%
Sigma-Aldrich
Bis(acetonitrile)(1,5-cyclooctadiene)rhodium(I)tetrafluoroborate