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  • Synthesis, characterization and antimicrobial properties of a Co(II)-phthalylsulfathiazolate complex.

Synthesis, characterization and antimicrobial properties of a Co(II)-phthalylsulfathiazolate complex.

Biometals : an international journal on the role of metal ions in biology, biochemistry, and medicine (2010-06-08)
Laura Monti, Ana Pontoriero, Natalia Mosconi, Cecilia Giulidori, Estela Hure, Patricia A M Williams, María Victoria Rodríguez, Gabriela Feresin, Darío Campagnoli, Marcela Rizzotto
ABSTRACT

The reaction between phthalylsulfathiazole (H(2)PST), in alkaline aqueous solution, and cobalt(II) nitrate led to a pink solid, [Co(PST)(H(2)O)(4)] (1), which was characterized by elemental and thermogravimetric analysis; FT-IR, Raman and diffuse reflectance spectra. Spectroscopic data reveal that the ligand would be doubly deprotonated and that the Co(II) ion environment is a distorted octahedral one. (1) showed antibacterial activity similar to the ligand.

MATERIALS
Product Number
Brand
Product Description

Sigma-Aldrich
Cobalt(II) nitrate hexahydrate, 99.999% trace metals basis
Sigma-Aldrich
Cobalt(II) nitrate hexahydrate, ACS reagent, ≥98%
Sigma-Aldrich
Cobalt(II) nitrate hexahydrate, reagent grade, 98%