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Biaryl phosphane ligands in palladium-catalyzed amination.

Angewandte Chemie (International ed. in English) (2008-07-30)
David S Surry, Stephen L Buchwald
ABSTRACT

Palladium-catalyzed amination reactions of aryl halides have undergone rapid development in the last 12 years, largely driven by the implementation of new classes of ligands. Biaryl phosphanes have proven to provide especially active catalysts in this context. This Review discusses the application of these catalysts in C-N cross-coupling reactions in the synthesis of heterocycles and pharmaceuticals, in materials science, and in natural product synthesis.

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SPhos Pd G1, Methyl t-Butyl Ether Adduct
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XPhos, 98%
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JohnPhos, 97%
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t-BuDavePhos
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sSPhos
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RuPhos Pd G1 Methyl -Butyl Ether Adduct, 95%
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tBuBrettPhos, 97%
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SPhos, 95%
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BrettPhos, 98%
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BrettPhos Pd G1, Methyl t-Butyl Ether Adduct, may contain up to 1 mole equivalent of MTBE, 97%
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Me4tButylXphos, 96%
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JackiePhos, 95%
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tBuXPhos Pd G1
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RuPhos, 98%
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DavePhos, 97%
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CyJohnPhos, 97%
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RuPhos ChemBeads
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