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Bupirimate

PESTANAL®, analytical standard

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About This Item

Empirical Formula (Hill Notation):
C13H24N4O3S
CAS Number:
41483-43-6
Molecular Weight:
316.42
Beilstein:
758056
EC Number:
255-391-2
MDL number:
MFCD00055518
UNSPSC Code:
41116107
PubChem Substance ID:
329753790
NACRES:
NA.24

grade

analytical standard

Quality Level

100

product line

PESTANAL®

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable
gas chromatography (GC): suitable

application(s)

agriculture
environmental

format

neat

storage temp.

2-8°C

SMILES string

CCCCc1c(C)nc(NCC)nc1OS(=O)(=O)N(C)C

InChI

1S/C13H24N4O3S/c1-6-8-9-11-10(3)15-13(14-7-2)16-12(11)20-21(18,19)17(4)5/h6-9H2,1-5H3,(H,14,15,16)

InChI key

DSKJPMWIHSOYEA-UHFFFAOYSA-N

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General description

Bupirimate is an active ingredient in plant protection products and is commonly used as a systemic fungicide. It belongs to the family of pyrimidines and finds applications in controlling powdery mildew in roses and apple plantations.

Application

Bupirimate may be used as a reference standard in the determination of bupirimate in fruits using gas chromatography coupled with a flame photometric detector (GC-FPD).
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

Signal Word

Warning

Hazard Statements

H312,H317,H351,H410

Hazard Classifications

Acute Tox. 4 Dermal - Aquatic Chronic 1 - Carc. 2 - Skin Sens. 1B

Storage Class Code

11 - Combustible Solids

WGK

WGK 2

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
BCCH2812
BCCH0089
BCCF5918
BCCD6163
BCBX0017

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S A Shahin et al.
Mutation research, 261(3), 169-176 (1991-11-01)
The 2 fungicides nimrod and rubigan-4 were tested for genotoxicity using Vicia faba root tips as the biological test system. Treating lateral roots with different concentrations of each fungicide for different periods showed that both fungicides were able to produce
Identification of pesticide transformation products in agricultural soils using liquid chromatography/quadrupole-time-of-flight mass spectrometry.
Padilla-Sanchez.AJ, et al.
Rapid Communications in Mass Spectrometry, 26(09), 1091-1099 (2012)
M J Jongen et al.
Journal of analytical toxicology, 16(1), 60-62 (1992-01-01)
An HPLC method was developed for estimation of dermal exposure of greenhouse workers to the pesticide bupirimate. Chromatography was performed on a cyano-modified silica column with methanol-water (6:4 by volume) containing 5 g/L ammonium sulfate as eluent. UV detection at
Allergic contact dermatitis from the fungicide bupirimate.
J P McFadden et al.
Contact dermatitis, 28(1), 47-47 (1993-01-01)
Bupirimate--a new fungicide for the control of powdery mildews on apples and other crops
R.JF, et al.
Proceedings of the British Insecticide and Fungicide Conference (1975)
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