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243272

Sigma-Aldrich

Allyl isocyanate

98%

Sinônimo(s):

3-Isocyanatoprop-1-ene

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About This Item

Fórmula linear:
CH2=CHCH2NCO
Número CAS:
1476-23-9
Peso molecular:
83.09
Beilstein:
506106
Número MDL:
MFCD00002044
Código UNSPSC:
12352100
ID de substância PubChem:
24854606
NACRES:
NA.22

Ensaio

98%

forma

liquid

índice de refração

n20/D 1.417 (lit.)

pb

87-89 °C (lit.)

densidade

0.94 g/mL at 25 °C (lit.)

temperatura de armazenamento

2-8°C

cadeia de caracteres SMILES

C=CCN=C=O

InChI

1S/C4H5NO/c1-2-3-5-4-6/h2H,1,3H2

chave InChI

HXBPYFMVGFDZFT-UHFFFAOYSA-N

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Descrição geral

The rate constants for the gas phase reactions of ozone, OH radical and NO(3) radical with allyl isocyanate (AIC) were studied.

Allyl isocyanate is an organosulfur compound that finds its application in the synthesis, and characterization of biodegradable dextran-allyl isocyanate-ethylamine/polyethylene glycol-diacrylate hydrogels.

Aplicação

Allyl isocyanate is used to prepare:
  • Allyl-pHPMA (allyl-Poly[N-(2-hydroxypropyl) methacrylamide) by reacting with 2° hydroxyl group of pHPMA.
  • Allyl-containing triBCP precursor via bidirectional anionic polymerization of styrene. The precursor used in the synthesis of poly(allyl isocyanate)-block-polystyrene-block-poly(allylisocyanate) (PAIC-b-PSt-b-PAIC).

Palavra indicadora

Danger

Classificações de perigo

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Eye Irrit. 2 - Flam. Liq. 3 - Resp. Sens. 1 - Skin Irrit. 2 - Skin Sens. 1

Código de classe de armazenamento

3 - Flammable liquids

Classe de risco de água (WGK)

WGK 3

Ponto de fulgor (°F)

109.4 °F - closed cup

Ponto de fulgor (°C)

43 °C - closed cup

Equipamento de proteção individual

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

Certificados de análise (COA)

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Sigma-Aldrich

483397

2-Bromoethyl isocyanate

European Journal of Organic Chemistry, 2649-2649 (2006)
Synthesis of Amphiphilic Helix--Coil--Helix Poly (3-(glycerylthio) propyl isocyanate)-block-polystyrene-block-poly (3-(glycerylthio) propyl isocyanate
Chae CG, et al.
Macromolecules, 51(3), 697-704 (2018)
José Miguel Arcas et al.
The Journal of neuroscience : the official journal of the Society for Neuroscience, 39(6), 949-969 (2018-12-14)
TRPM8 is a polymodal, nonselective cation channel activated by cold temperature and cooling agents that plays a critical role in the detection of environmental cold. We found that TRPM8 is a pharmacological target of tacrolimus (FK506), a macrolide immunosuppressant with
Rui Guo et al.
Journal of applied biomaterials & functional materials, 13(3), e228-e233 (2015-09-10)
This study reports on the synthesis and characterization of biodegradable dextran-allyl isocyanate-ethylamine (Dex-AE)/polyethylene glycol-diacrylate (PEGDA) hydrogels for the controlled release of gentamycin sulphate (GS) and in vitro inhibition of organisms. The Dex-AE precursor was prepared through a 2-step chemical modification
James K Parker et al.
The journal of physical chemistry. A, 113(36), 9814-9824 (2009-09-04)
Rate constants for the gas-phase reactions of OH radical, NO(3) radical, and ozone with allyl alcohol (AAL) and allyl isocyanate (AIC) have been measured using relative rate methods at atmospheric pressure in purified air. The experimental Arrhenius expression obtained for
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