Asymmetric palladium-catalysed intramolecular Wacker-type cyclisations of unsaturated alcohols and amino alcohols.

Asymmetric palladium-catalysed intramolecular Wacker-type cyclisations of unsaturated alcohols and amino alcohols.

Molecules (Basel, Switzerland) (2013-05-28)

Jana Doháňošová, Tibor Gracza

ABSTRACT

The palladium (II)-catalysed reactions of alkenols and aminoalkenols such as oxycarbonylations or bicyclisations are powerful methods for the construction of oxygen and nitrogen-containing heterocyclic compounds. This review highlights recent progress in the development of the asymmetric palladium(II)-catalysed Wacker-type cyclisations of unsaturated polyols and aminoalcohols. The scope, limitations, and applications of these reactions are presented.

MATERIALS

Product Number

Brand

Product Description

GF55245821

Palladium, foil, not light tested, 100x100mm, thickness 0.025mm, as rolled, 99.99+%

GF57528816

Palladium, foil, not light tested, 25x25mm, thickness 0.006mm, 99.95%

GF69074916

Palladium, foil, not light tested, 25x25mm, thickness 0.00075mm, permanent polyester support, 99.75%

GF55924241

Palladium, foil, not light tested, 25x25mm, thickness 0.025mm, as rolled, 99.99+%

GF60234533

Palladium, foil, 8mm disks, thickness 0.25mm, as rolled, 99.99+%

GF23374661

Palladium, foil, 8mm disks, thickness 0.50mm, as rolled, 99.95%

GF90427866

Palladium, foil, light tested, 100x100mm, thickness 0.025mm, as rolled, 99.95%

GF60084424

Palladium, foil, light tested, 100x100mm, thickness 0.025mm, as rolled, 99.99+%

GF74894136

Palladium, foil, 8mm disks, thickness 0.25mm, as rolled, 99.95%

GF44874995

Palladium, foil, light tested, 100x100mm, thickness 0.047mm, as rolled, 99.95%

GF94632576

Palladium, foil, light tested, 100x100mm, thickness 0.075mm, as rolled, 99.95%

GF01094374

Palladium, foil, 8mm disks, thickness 0.0125mm, 99.95%

GF47081437

Palladium, foil, not light tested, 150x150mm, thickness 0.025mm, as rolled, 99.95%

GF52930762

Palladium, microfoil, disks, 10mm, thinness 0.5μm, specific density 303.4μg/cm², permanent mylar 3.5μm support, 99.99%

GF38967193

Palladium, foil, not light tested, 25x25mm, thickness 0.03mm, as rolled, 99.95%

GF15900713

Palladium, microfoil, disks, 25mm, thinness 0.5μm, specific density 303.4μg/cm², permanent mylar 3.5μm support, 99.99%

GF16402586

Palladium, foil, not light tested, 25x25mm, thickness 0.002mm, 99.95%

GF23734065

Palladium, foil, not light tested, 25x25mm, thickness 0.005mm, 99.95%

GF73152648

Palladium, rod, 10mm, diameter 6.0mm, 99.95%

GF12546581

Palladium, wire reel, 0.1m, diameter 0.25mm, hard, 99.95%

GF38432336

Palladium, wire reel, 0.5m, diameter 0.05mm, as drawn, 99.9%

GF11001564

Palladium, microfoil, disks, 25mm, thinness 0.05μm, specific density 63.6μg/cm², permanent mylar 3.5μm support, 99.99%

GF39094904

Palladium, tube, 50mm, outside diameter 1.0mm, inside diameter 0.8mm, wall thickness 0.1mm, as drawn, 99.95%

GF43081174

Palladium, foil, not light tested, 100x100mm, thickness 0.0125mm, 99.95%

GF99300371

Palladium, wire reel, 50m, diameter 0.125mm, hard, 99.95%

GF94883822

Palladium, rod, 25mm, diameter 2.0mm, 99.95%

GF22660264

Palladium, wire reel, 0.1m, diameter 0.5mm, as drawn, 99.95%

GF59343688

Palladium, foil, not light tested, 50x50mm, thickness 0.0125mm, 99.95%

GF96367977

Palladium, foil, not light tested, 25x25mm, thickness 0.001mm, permanent polyester support, 99.75%

GF85707513

Palladium, wire reel, 0.5m, diameter 1.0mm, hard, 99.95%