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119342

Sigma-Aldrich

(Dimethylaminomethyl)ferrocene

≥95%

Synonyme(s) :

(Ferrocenylmethyl)dimethylamine, Ferrocenemethylamine, N,N-Dimethylferrocenylmethylamine

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About This Item

Formule empirique (notation de Hill):
C13H17FeN
Numéro CAS:
1271-86-9
Poids moléculaire :
243.13
Numéro CE :
215-044-8
Numéro MDL:
MFCD00001433
Code UNSPSC :
12161600
ID de substance PubChem :
24847394
Nomenclature NACRES :
NA.22

Pureté

≥95%

Pertinence de la réaction

core: iron
reagent type: catalyst

Indice de réfraction

n20/D 1.59 (lit.)

Point d'ébullition

124-128 °C/2.5 mmHg (lit.)

Densité

1.228 g/mL at 25 °C (lit.)

Température de stockage

2-8°C

Chaîne SMILES 

[Fe].[CH]1[CH][CH][CH][CH]1.CN(C)C[C]2[CH][CH][CH][CH]2

InChI

1S/C8H12N.C5H5.Fe/c1-9(2)7-8-5-3-4-6-8;1-2-4-5-3-1;/h3-6H,7H2,1-2H3;1-5H;

Clé InChI

JJJSTEANRWLZBH-UHFFFAOYSA-N

Catégories apparentées

Description générale

(Dimethylaminomethyl) ferrocene (DMAMF) is a ferrocene with a dimethylaminomethyl substituent attached to one of the cyclopentadienyl ligands. It can be used as a precursor in the preparation of iron oxide-based films.

Application

(Dimethylaminomethyl)ferrocene can be used as:
  • A Precursor in the preparation of iron oxide and magnesium-doped iron oxide films by atomic layer deposition (ALD).
  • An amine ligand in the synthesis of pentacarbonyl{[(dimethylamino)methyl]ferrocene}tungsten complex.

Code de la classe de stockage

10 - Combustible liquids

Classe de danger pour l'eau (WGK)

WGK 3

Point d'éclair (°F)

235.4 °F - closed cup

Point d'éclair (°C)

113 °C - closed cup

Équipement de protection individuelle

Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)

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V N Goral et al.
Biochemistry and molecular biology international, 45(1), 61-71 (1998-06-23)
Reactivity of horseradish peroxidase compounds I and II (HRP-I and HRP-II) toward organometallicic substrates, viz water-soluble ferrocenes RFc (R = COOH and CH2NMe2), has been studied at 25 degrees C, pH 6.0 and ionic strength 0.1 M. The second-order rate
S Takenaka et al.
Analytical biochemistry, 218(2), 436-443 (1994-05-01)
Electrochemically active DNA probes were prepared by linking a ferrocene unit with 5'-aminohexyl-terminated oligonucleotides. The DNA sequences of probes 5a, 5b, and 5c were 5'-T12-3', 5'-T20-3', and 5'-TGCAG TTCCG GTGGC TGATC-3', respectively. Probe 5a could form a complex selectively with
Guozhen Liu et al.
Analytica chimica acta, 909, 1-8 (2016-02-07)
A stable label-free amperometric immunosensor is presented based on gold nanoparticles and graphene oxide nanocomposites for detection of cardiac troponin-I in the early diagnosis of myocardial infarction. For designing of the sensing platform, firstly the nanocomposites based on GO and
Yoshihiro Kase et al.
Analytical sciences : the international journal of the Japan Society for Analytical Chemistry, 20(8), 1143-1146 (2004-09-09)
We propose an electron transfer-mediated amperometric enzyme biosensor based on plasma-polymerized thin film of dimethylaminomethylferrocene (DMAMF) on a sputtered gold electrode. The DMAMF plasma-polymerized film is deposited directly onto the surface of the electrode under dry conditions. The resulting thin
A N Shevel'kova et al.
Biokhimiia (Moscow, Russia), 58(6), 928-937 (1993-06-01)
The effects of dimethylaminomethylferrocene (DMAMF) on amylose and maltodextrins destruction by gluco-, alpha- and beta-amylases have been studied. The nature of DMAMF effects depends on the action mechanism of amylases and structure of their active sites. The effect observed is
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