- First mixed hydrazide/hydroxylamide metal aggregates.
First mixed hydrazide/hydroxylamide metal aggregates.
Chemical communications (Cambridge, England) (2006-09-28)
Surajit Jana, Raphael J F Berger, Roland Fröhlich, Norbert W Mitzel
PMID17003876
ABSTRACT
The first organometallic clusters of mixed hydrazide/hydroxylamide clusters of zinc, [Zn(MeZn)(4)(HNNMe(2))(2)(ONEt(2))(4)] and {Zn(EtZn)(4)[HNN(CH(2))(5)](2)(ONEt(2))(4)} were synthesized in one-pot synthesis protocols from dialkylzinc solutions, substituted hydrazines and N,N-diethylhydroxylamine; competing for the Zn atoms, the different binding properties of hydrazide and hydroxylamide ligands in these heteroleptic clusters are discussed.
MATERIALS