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116157

Sigma-Aldrich

1,4-Dibromo-2,5-dimethylbenzene

98%

Synonym(s):

2,5-Dibromo-p-xylene

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About This Item

Linear Formula:
(CH3)2C6H2Br2
CAS Number:
1074-24-4
Molecular Weight:
263.96
EC Number:
214-038-2
MDL number:
MFCD00000091
UNSPSC Code:
12352100
PubChem Substance ID:
24847267
NACRES:
NA.22

Assay

98%

form

solid

bp

261 °C (lit.)

mp

72-74 °C (lit.)

SMILES string

Cc1cc(Br)c(C)cc1Br

InChI

1S/C8H8Br2/c1-5-3-8(10)6(2)4-7(5)9/h3-4H,1-2H3

InChI key

QENIALCDPFDFHX-UHFFFAOYSA-N

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Application

1,4-dibromo-2,5-dimethylbenzene has been used in the preparation of 4,4″-diformyl-2′,5′-dimethyl-1,1′.4′,1″-terphenyl. It has also been used in the preparation of 1,4-diformyl-2,5-dimethylbenzene.

Pictograms

Exclamation markEnvironment
GHS07,GHS09

Signal Word

Warning

Hazard Statements

H315,H319,H335,H411

Hazard Classifications

Aquatic Chronic 2 - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

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The synthesis of aromatic dicarboxaldehydes, using dilithiation methodology is described along with their reactivity, in the [3 + 3] cyclocondensation reaction, with (1R,2R)-diaminocyclohexane to give trianglimine macrocycles. The scope and limitations of the cyclocondensation reaction are studied and some comments
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Nikolai Kuhnert et al.
Organic & biomolecular chemistry, 3(10), 1911-1921 (2005-05-13)
The synthesis of aromatic dicarboxaldehydes is described along with their reactivity in the [3 + 3] cyclocondensation reaction with (1R,2R)-diaminocyclohexane to give trianglimine macrocycles. In particular, the scope and limitation of the reaction with regard to complete control of the

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