701629

Bis(1,5-cyclooctadiene)rhodium(I) hexafluoroantimonate

97%

• Empirical Formula (Hill Notation): C₁₆H₂₄F₆RhSb
• CAS Number: 130296-28-5
• Molecular Weight: 555.02
• MDL number: MFCD11113031
• UNSPSC Code: 12161600
• PubChem Substance ID: 329762310
• NACRES: NA.22

Properties

• Assay: 97%
• form: powder
• reaction suitability: core: rhodium; reagent type: catalyst
• mp: 58-60 °C
• storage temp.: −20°C
• SMILES string: [Rh+].F[Sb-](F)(F)(F)(F)F.C1CC=CCCC=C1.C2CC=CCCC=C2
• InChI: 1S/2C8H12.6FH.Rh.Sb/c2*1-2-4-6-8-7-5-3-1;;;;;;;;/h2*1-2,7-8H,3-6H2;6*1H;;/q;;;;;;;;+1;+5/p-6/b2*2-1-,8-7-;;;;;;;;
• InChI key: BROZUPPJWNODCU-SXGOCSEPSA-H

Description

Application

Catalyst for:

• [3+2] Cycloaddition
• Preparation of diastereomeric chiral phosphorus mon- and bidentate diamidophosphite ligands based on dianydromannitol and their use in asymmetric metallocomplex catalysis
• C-C bond-forming hydrogenation

Safety Information

• Pictograms: GHS07,GHS09
• Signal Word: Warning
• Hazard Statements: H302 + H332,H411
• Precautionary Statements: P261 - P264 - P271 - P273 - P301 + P312 - P304 + P340 + P312
• Hazard Classifications: Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 2
• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves