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229652

Sigma-Aldrich

Hafnium(IV) oxychloride hydrate

99.99% trace metals basis (purity excludes zirconium)

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About This Item

Linear Formula:
HfOCl2 · xH2O
CAS Number:
Molecular Weight:
265.40 (anhydrous basis)
EC Number:
MDL number:
UNSPSC Code:
12352302
PubChem Substance ID:
NACRES:
NA.23

Quality Level

Assay

99.99% trace metals basis (purity excludes zirconium)

form

crystalline

impurities

≤200.0 ppm Trace Metal Analysis

SMILES string

O.Cl[Hf](Cl)=O

InChI

1S/2ClH.Hf.H2O.O/h2*1H;;1H2;/q;;+2;;/p-2

InChI key

ONMNZQKEFYFCCQ-UHFFFAOYSA-L

General description

Degree of hydration 6-8

Application

Starting material for HfGeO4 and HfGeO4:Ti, both used in x-ray phosphors.

Pictograms

Corrosion

Signal Word

Danger

Hazard Statements

Hazard Classifications

Skin Corr. 1B

Storage Class Code

8B - Non-combustible corrosive hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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P. M. Lambert
Inorganic chemistry, 37(6), 1352-1357 (2001-10-24)
The gel chemistry of germanium is explored through the formation and composition of a hydrous metal oxide precursor gel used in the preparation of the HfGeO(4) and HfGeO(4):Ti X-ray phosphors. The enhanced solubility of hexagonal GeO(2) in dilute ammoniacal solutions

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