- FeCl3 catalyzed Prins-type cyclization for the synthesis of highly substituted indenes: application to the total synthesis of (±)-jungianol and epi-jungianol.
FeCl3 catalyzed Prins-type cyclization for the synthesis of highly substituted indenes: application to the total synthesis of (±)-jungianol and epi-jungianol.
Organic letters (2013-01-16)
Dattatraya H Dethe, Ganesh Murhade
PMID23317410
ZUSAMMENFASSUNG
A novel approach was developed for the synthesis of highly substituted indene derivatives, using an FeCl(3) catalyzed Prins-type cyclization reaction which was further applied in the total synthesis of jungianol and epi-jungianol.
MATERIALIEN
Produktnummer
Marke
Produktbeschreibung
Sigma-Aldrich
Eisen(III)-chlorid Hexahydrat, puriss. p.a., ACS reagent, crystallized, 98.0-102% (RT)