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Diastereoselective solid-phase radical addition to oxime ether anchored to polymer support.

Chemical & pharmaceutical bulletin (2003-05-09)
Hideto Miyabe, Chihiro Konishi, Takeaki Naito
ZUSAMMENFASSUNG

Stereocontrol in radical reactions of oxime ether anchored to polymer support was studied. Highly diastereoselective solid-phase radical reaction was achieved by using triethylborane and diethylzinc as a radical initiator at low reaction temperature, providing a novel method for the synthesis of the alpha-amino acid derivatives with excellent diastereoselectivities.

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Sigma-Aldrich
Triethylboran -Lösung, 1.0 M in THF
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Sigma-Aldrich
Triethylboran -Lösung, 1.0 M in hexanes
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