802425

2-Bromo-1,10-phenanthroline

• Empirische Formel (Hill-System): C₁₂H₇BrN₂
• CAS-Nummer: 22426-14-8
• Molekulargewicht: 259.10
• MDL-Nummer: MFCD13152102
• UNSPSC-Code: 12352100
• PubChem Substanz-ID: 329768737
• NACRES: NA.22

Eigenschaften

• Form: powder
• Qualitätsniveau: 100
• mp (Schmelzpunkt): 160-165 °C
• Funktionelle Gruppe: bromo
• SMILES String: BrC1=NC2=C(N=CC=C3)C3=CC=C2C=C1
• InChI: 1S/C12H7BrN2/c13-10-6-5-9-4-3-8-2-1-7-14-11(8)12(9)15-10/h1-7H
• InChIKey: ZRJUDAZGVGIDLP-UHFFFAOYSA-N

Beschreibung

Anwendung

Brominated phenanthroline can be synthesized via a method reported by Baran and coworkers using a two-step protocol through N-Oxide formation using m-CBPA (Aldrich 273031) and bromination using TBAB (Sigma-Aldrich 426288) and p-Toluenesulfonic anhydride (Aldrich 259764).

Sonstige Hinweise

Regioselective Bromination of Fused Heterocyclic N-Oxides

Sicherheitshinweise

• Piktogramme: GHS06,GHS05,GHS09
• Signalwort: Danger
• H-Sätze: H301,H315,H318,H410
• P-Sätze: P273 - P280 - P301 + P310 + P330 - P302 + P352 - P305 + P351 + P338 + P310
• Gefahreneinstufungen: Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Irrit. 2
• Lagerklassenschlüssel: 6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
• WGK: WGK 3
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable