255025

Hexylmagnesiumbromid -Lösung

2.0 M in diethyl ether

• Synonym(e): 1-Hexylmagnesium bromide, Bromohexylmagnesium, n-hexylmagnesium bromide
• Lineare Formel: CH₃(CH₂)₅MgBr
• CAS-Nummer: 3761-92-0
• Molekulargewicht: 189.38
• Beilstein: 3535624
• MDL-Nummer: MFCD00000046
• UNSPSC-Code: 12352103
• PubChem Substanz-ID: 24855279
• NACRES: NA.22

Eigenschaften

• Eignung der Reaktion: reaction type: Grignard Reaction
• Konzentration: 2.0 M in diethyl ether
• Dichte: 0.965 g/mL at 25 °C
• SMILES String: CCCCCC[Mg]Br
• InChI: 1S/C6H13.BrH.Mg/c1-3-5-6-4-2;;/h1,3-6H2,2H3;1H;/q;;+1/p-1
• InChIKey: SFXUWNMDTWQSHE-UHFFFAOYSA-M

Beschreibung

Allgemeine Beschreibung

Hexylmagnesium bromide, also known as n-hexylmagnesium bromide, is a useful organomagnesium compound that is commonly used in organic synthesis. It is typically prepared by reacting magnesium turnings with 1-bromohexane in diethyl ether solvent.

Anwendung

Hexylmagnesium bromide solution can be used as a reagent in addition reactions. It can add to various electrophiles, such as carbonyl compounds, to form alcohols or carboxylic acids. These types of reactions are commonly used for the synthesis of pharmaceuticals, natural products, and other organic compounds. It is also used to reduce certain functional groups, such as ketones, esters, and nitriles, to form alcohols or amines.

Sicherheitshinweise

• Piktogramme: GHS02,GHS05,GHS07
• Signalwort: Danger
• H-Sätze: H225,H260,H302,H314,H336
• P-Sätze: P210 - P231 + P232 - P280 - P301 + P312 - P303 + P361 + P353 - P305 + P351 + P338
• Gefahreneinstufungen: Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3 - Water-react 1
• Zielorgane: Central nervous system
• Zusätzliche Gefahrenhinweise: EUH019
• Lagerklassenschlüssel: 4.3 - Hazardous materials which set free flammable gases upon contact with water
• WGK: WGK 3
• Flammpunkt (°F): -40.0 °F - closed cup
• Flammpunkt (°C): -40 °C - closed cup
• Persönliche Schutzausrüstung: Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter