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Sigma-Aldrich

Hexachlor-2-Propanon

produced by Wacker Chemie AG, Burghausen, Germany, ≥99.0% (GC)

Synonym(e):

HCA, Hexachloraceton

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About This Item

Lineare Formel:
CCl3COCCl3
CAS-Nummer:
116-16-5
Molekulargewicht:
264.75
Beilstein:
1707475
EG-Nummer:
204-129-5
MDL-Nummer:
MFCD00000796
UNSPSC-Code:
12352100
PubChem Substanz-ID:
57646830
NACRES:
NA.22

Qualität

produced by Wacker Chemie AG, Burghausen, Germany

Qualitätsniveau

100

Assay

≥99.0% (GC)

Brechungsindex

n20/D 1.511 (lit.)

bp

66-70 °C/6 mmHg (lit.)

mp (Schmelzpunkt)

−6-−2 °C (lit.)

Dichte

1.743 g/mL at 25 °C (lit.)

Anwendung(en)

agriculture
environmental

SMILES String

ClC(Cl)(Cl)C(=O)C(Cl)(Cl)Cl

InChI

1S/C3Cl6O/c4-2(5,6)1(10)3(7,8)9

InChIKey

DOJXGHGHTWFZHK-UHFFFAOYSA-N

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Verwandte Kategorien

Allgemeine Beschreibung

Hexachloro-2-propanone is a colorless liquid. It is present in herbicide Bromacil formulation. Hexachloro-2-propanone is precursor for the generation and cycloaddition of oxyallyl intermediates. It reverts the Ames strains TA98 and TA100 but not the non-plasmid strains TA1537, TA1535 and TA1538.

Anwendung

Hexachloro-2-propanone (hexachloroacetone) was used in the synthesis of chirally deuterated benzyl chlorides and enol phosphate 2,2-dichloro-1-(trichloromethyl)ethenyl diethyl phosphate. It was also used in obtaining efficient amino acid activation by exploiting the rapid formation of acid chlorides under low temperature and acid/base free conditions.

Sonstige Hinweise

Preise für Bulkgebinde auf Anfrage

Piktogramme

Skull and crossbonesEnvironment
GHS06,GHS09

Signalwort

Danger

Gefahreneinstufungen

Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 2 - Skin Sens. 1

Lagerklassenschlüssel

6.1C - Combustible, acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 2

Flammpunkt (°F)

235.4 °F - closed cup

Flammpunkt (°C)

113 °C - closed cup

Persönliche Schutzausrüstung

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

Analysenzertifikate (COA)

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Baldur Föhlisch et al.
Molecules (Basel, Switzerland), 9(1), 1-10 (2007-11-17)
The enol phosphate 2,2-dichloro-1-(trichloromethyl)ethenyl diethyl phosphate (1), easily available by a Perkow reaction between hexachloroacetone and triethyl phosphite, reacts with sodium trifluoroethoxide/trifluoroethanol in the presence of cyclic 5-membered 1,3-dienes to furnish alpha,alpha,alpha',alpha'-tetrachloro-substituted[3.2.1]bicyclic ketones 2. A [4+3] cycloaddition of a tetrachloro-oxyallyl
E R Nestmann et al.
Environmental mutagenesis, 7(2), 163-170 (1985-01-01)
Reports in the literature describing artifactual results owing to interactions of test materials with solvents are becoming more frequent. The present study was initiated to examine possible interactions of 1,1,3-trichloro-, 1,1,3,3-tetrachloro-, pentachloro- and hexachloroacetones with different solvents, since certain solvent
Konstantina Sargenti et al.
Liver international : official journal of the International Association for the Study of the Liver, 35(2), 391-400 (2014-07-22)
Population-based data on the occurrence of healthcare-associated (HCA) and hospital-acquired (HA) bacterial infections in cirrhosis, their predictors, and their impact on outcome are limited. All patients with incident cirrhosis in 2001-2010 residing in an area of 600,000 inhabitants were retrospectively
Marian Kacerovsky et al.
The journal of maternal-fetal & neonatal medicine : the official journal of the European Association of Perinatal Medicine, the Federation of Asia and Oceania Perinatal Societies, the International Society of Perinatal Obstetricians, 28(2), 134-140 (2014-03-29)
Abstract Objective: To determine the cervical fluid interleukin (IL)-6 and IL-8 levels in pregnancies complicated by preterm prelabor rupture of membranes (PPROM) and the association of these interleukins with microbial invasion of the amniotic cavity (MIAC) and histological chorioamnionitis (HCA).
Determination of hexachloroacetone in air.
E Kissa
Analytical chemistry, 55(8), 1222-1225 (1983-07-01)
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