Accessing Stable Magnesium Acyl Compounds: Reductive Cleavage of Esters by Magnesium(I) Dimers.

Accessing Stable Magnesium Acyl Compounds: Reductive Cleavage of Esters by Magnesium(I) Dimers.

Chemistry (Weinheim an der Bergstrasse, Germany) (2017-09-07)

Aaron J Boutland, Carlos A Lamsfus, Brant Maitland, Laurent Maron, Andreas Stasch, Cameron Jones

RESUMEN

The first examples of magnesium acyls, [(Nacnac)Mg{μ-C(Ph)O}(μ-OR)Mg(Nacnac)] (R=Me, tBu or Ph; Nacnac=[HC(MeCNAr)

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Sigma-Aldrich

Nitrogen-¹⁴N₂, 99.99 atom % ¹⁴N