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361267

Sigma-Aldrich

cis-1,2-Cyclohexanediol

99%

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About This Item

Fórmula lineal:
C6H10(OH)2
Número de CAS:
1792-81-0
Peso molecular:
116.16
Beilstein/REAXYS Number:
1340578
MDL number:
MFCD00064944
UNSPSC Code:
12352100
PubChem Substance ID:
24862178
NACRES:
NA.22

assay

99%

mp

97-101 °C (lit.)

SMILES string

O[C@@H]1CCCC[C@@H]1O

InChI

1S/C6H12O2/c7-5-3-1-2-4-6(5)8/h5-8H,1-4H2/t5-,6+

InChI key

PFURGBBHAOXLIO-OLQVQODUSA-N

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General description

Core-shell-like silica nickel species nanoparticle catalyzed dehydrogenation of 1,2-cyclohexanediol to catechol is reported. Crystal structure of a Cr(V) complex with cis-1,2-cyclohexanediol is reported. Enzymatic oxidation of cis-1,2-cyclohexanediol by Gluconobacter oxydans (ATCC 621) is reported.

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

Certificados de análisis (COA)

Busque Certificados de análisis (COA) introduciendo el número de lote del producto. Los números de lote se encuentran en la etiqueta del producto después de las palabras «Lot» o «Batch»

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1,2-Cyclohexanedione 97%

Sigma-Aldrich

C101400

1,2-Cyclohexanedione

Bismuth(III) nitrate pentahydrate ACS reagent, ≥98.0%

Sigma-Aldrich

383074

Bismuth(III) nitrate pentahydrate

Bao-Hui Chen et al.
Dalton transactions (Cambridge, England : 2003), 44(3), 1023-1038 (2014-11-20)
A simple and convenient approach denoted as gel-deposition-precipitation (G-D-P) for the preparation of core-shell-like silica@nickel species nanoparticles was studied systematically. Core-shell-like silica@nickel species nanoparticles consisted of a Si-rich core and a Ni-rich shell. The G-D-P process included two steps: one
Oxidation of trans-and cis-1, 2-cyclohexanediol by Gluconobacter oxydans.
Adlercreutz P.
Applied Microbiology and Biotechnology, 30(3), 257-263 (1989)
Ruben Bartholomäus et al.
Inorganic chemistry, 52(8), 4282-4292 (2013-03-28)
The stabilization of Cr(V) by biological 1,2-diolato ligands, including carbohydrates, glycoproteins, and sialic acid derivatives, is likely to play a crucial role in the genotoxicity of Cr(VI) and has also been implicated in the antidiabetic effect of Cr(III). Previously, such
T Kiguchi et al.
Chemical & pharmaceutical bulletin, 48(10), 1536-1540 (2000-10-25)
Asymmetric spirocyclization based on intramolecular conjugate addition using a combination of a Lewis acid and an optically active cyclohexane-1,2-diol has been studied in connection with 1) the effect of substituents on the cyclohexane-1,2-diol and 2) the effect of substituents on
Ivan Liashkovich et al.
Journal of controlled release : official journal of the Controlled Release Society, 160(3), 601-608 (2012-03-06)
The efficiency of gene therapy in non-dividing cells is particularly poor due to restricted nuclear delivery rates of exogenously applied macromolecules across the nuclear pore complexes (NPCs). Therefore, improved intranuclear delivery of transgenes requires an ability to modulate the barrier
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