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125482

Sigma-Aldrich

cis-Cyclooctene

contains 100-200 ppm Irganox 1076 FD as antioxidant, 95%

Sinónimos:

(Z)-Cyclooctene

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About This Item

Fórmula empírica (notación de Hill):
C8H14
Número de CAS:
931-87-3
Peso molecular:
110.20
EC Number:
213-243-4
MDL number:
MFCD00001753
UNSPSC Code:
12352100
PubChem Substance ID:
24847668
NACRES:
NA.22

Quality Level

100

assay

95%

form

liquid

contains

100-200 ppm Irganox 1076 FD as antioxidant

refractive index

n20/D 1.469 (lit.)

bp

145-146 °C (lit.)

mp

−16 °C (lit.)

solubility

H2O: insoluble

density

0.846 g/mL at 25 °C (lit.)

SMILES string

C1CCCC=CCC1

InChI

1S/C8H14/c1-2-4-6-8-7-5-3-1/h1-2H,3-8H2/b2-1-

InChI key

URYYVOIYTNXXBN-UPHRSURJSA-N

General description

cis-Cyclooctene undergoes addition reaction with carbon tetrachloride catalyzed by dichlorotris(triphenylphosphine) ruthenium(II) to yield 1-chloro-4-(trichloromethyl) cyclooctane (1,4-adduct). It undergoes epoxidation catalyzed by molybdenum oxide nanoparticles incorporated in a mesoporous silica shell coated on dense silica-coated magnetite nanoparticles.

Application

cis-Cyclooctene has been used to study the alkenes chemisorbed on silicon(100) by scanning tunneling microscopy.

Other Notes

Contains cyclooctane

pictograms

Flame
GHS02

signalword

Warning

hcodes

H226

Hazard Classifications

Flam. Liq. 3

Storage Class

3 - Flammable liquids

wgk_germany

WGK 2

flash_point_f

77.0 °F - closed cup

flash_point_c

25 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

Certificados de análisis (COA)

Busque Certificados de análisis (COA) introduciendo el número de lote del producto. Los números de lote se encuentran en la etiqueta del producto después de las palabras «Lot» o «Batch»

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A magnetically recyclable nanocomposite catalyst for olefin epoxidation.
Mohammadreza Shokouhimehr et al.
Angewandte Chemie (International ed. in English), 46(37), 7039-7043 (2007-08-10)
Voltage-dependent STM images of covalently bound molecules on Si (100).
Padowitz DF and Hamers RJ.
The Journal of Physical Chemistry B, 102(43), 8541-8545 (1998)
Radical reactions in the coordination sphere. 4. Addition of carbon tetrachloride to cis-cyclooctene catalyzed by dichlorotris (triphenylphosphine) ruthenium (II).
Matsumoto H, et al.
The Journal of Organic Chemistry, 43(9), 1734-1736 (1978)
Xiao-Song Xue et al.
Chemical reviews, 117(13), 8622-8648 (2017-03-11)
The most fundamental concepts in chemistry are structure, energetics, reactivity and their inter-relationships, which are indispensable for promoting chemistry into a rational science. In this regard, bond energy, the intrinsic determinant directly related to structure and reactivity, should be most
Andrey B Lysenko et al.
Inorganic chemistry, 58(24), 16424-16433 (2019-11-26)
3-(1,2,4-Triazol-4-yl)adamantane-1-carboxylic acid (tradcH), a heterobifunctional organic ligand in which carboxylic acid and 1,2,4-triazole groups are united through a rigid 1,3-adamantanediyl spacer, was employed for the synthesis of a MoVI oxide organic hybrid. The ligand crystallized from water as tradcH·H2O (1)
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