- The first example of erbium triple-stranded helicates displaying SMM behaviour.
The first example of erbium triple-stranded helicates displaying SMM behaviour.
Dalton transactions (Cambridge, England : 2003) (2015-09-09)
Adam Gorczyński, Maciej Kubicki, Dawid Pinkowicz, Robert Pełka, Violetta Patroniak, Robert Podgajny
PMID26346821
ABSTRACT
A series of isostructural C3-symmetrical triple stranded dinuclear lanthanide [Ln2L3](NO3)3 molecules have been synthesized using subcomponent self-assembly of Ln(NO3)3 with 2-(methylhydrazino)benzimidazole and 4-tert-butyl-2,6-diformylphenol, where Ln = Tb (1), Dy (2), Ho (3), Er (4), Tm (5), and Yb (6). The temperature dependent and field dependent magnetic properties of 1-6 were modeled using the van Vleck approximation including the crystal field term HCF, the super-exchange term HSE and the Zeeman term HZE. Ferromagnetic interactions were found in 1, 2, 4 and 6, while antiferromagnetic interactions were found in 3 and 5. The erbium analogue reveals field induced SMM behaviour.