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Dermatitis in workers exposed to antimony in a melting process.

Journal of occupational medicine. : official publication of the Industrial Medical Association (1993-04-01)
G P White, C G Mathias, J S Davin
ABSTRACT

An employee at a brazing rod manufacturing plant developed a generalized eruption of follicular papules and pustules. His job tasks included breaking up antimony ingots and melting the pieces in a crucible; he was exposed to antimony metal dust and to antimony trioxide fumes. Two fellow employees who later performed the same job tasks developed similar eruptions. The clinical and workplace evaluations suggested that the fumes from melting antimony were the cause of the dermatoses, and that the current Occupational Safety and Health Administration permissible exposure limit is not adequate to prevent cutaneous effects of antimony exposure.

MATERIALS
Product Number
Brand
Product Description

Sigma-Aldrich
Antimony(III) oxide, nanopowder, <250 nm particle size (TEM), ≥99.9% trace metals basis
Sigma-Aldrich
Antimony(III) oxide, 99.99% trace metals basis
Sigma-Aldrich
Antimony(III) oxide, 99.999% trace metals basis
Sigma-Aldrich
Antimony(III) oxide, powder, 5 μm, ReagentPlus®, 99%